Hydroxyl stretching in phyllosilicates at high pressures and temperatures: an infrared spectroscopic study     

Alison R. Pawley  Raymond L. Jones 《Physics and Chemistry of Minerals》2011,38(10):753-765

The hydroxyl stretching frequencies of four phyllosilicates have been measured at high pressures and temperatures using an externally heated diamond-anvil cell and synchrotron infrared spectroscopy. Spectra were measured up to 26, 31, 21 and 8 GPa at room temperature for samples of talc, pyrophyllite, muscovite and 10-Å phase, respectively. Spectra were also measured in the range 273–500 K at ambient pressure for all samples and at 8–9 GPa for talc and pyrophyllite. The frequency of the Mg₃OH band in talc increases with pressure due to the absence of hydrogen bonding. The different orientation of the hydroxyl group in pyrophyllite and muscovite leads to hydrogen bonding and a decrease in the frequency of the Al₂OH band with pressure. 10-Å phase is approximately equivalent to talc with the addition of interlayer H₂O. In a spectrum of a sample synthesised for 143 h, two hydroxyl stretching bands are clearly resolved on compression. One is the same as the Mg₃OH band in talc, indicating the presence of intra-layer hydroxyl in a talc-like environment with no hydrogen bonding. The other, which separates from the talc-like band at 1 GPa, is associated with intra-layer hydroxyl that is hydrogen bonded to interlayer H₂O. There are equivalent bands in high-pressure spectra of a sample of deuterated 10-Å phase, synthesised for 400 h. This sample shows a greater extent of hydrogen bonding at ambient pressure than the 143 h sample. For all of the phases studied, increasing temperature leads to a decrease in frequency for every hydroxyl stretching vibration, both at low and high pressures. The shifts in frequency with temperature are an order of magnitude greater than the shifts with pressure when normalised to previously measured structural parameters.  相似文献   

Comment on “Formation of Thetis Deep metal-rich sediments in the absence of brines,Red Sea” by     

Neil C. Mitchell  Mark Schmidt  Marco Ligi 《Journal of Geochemical Exploration》2011

  相似文献   

Effect of highly pervious geological features on ground-water flow into a tunnel     

J. Moon  S. Jeong 《Engineering Geology》2011,117(3-4):207-216

Current practice for estimating water inflow rate relies mostly on analytical solutions which assume a homogeneous, isotropic porous medium around a tunnel. Field measurements indicate that current engineering practice does not consistently make adequate estimate of ground-water flow into a tunnel during excavation due to various factors that analytical solutions do not properly take into account. Among the various factors affecting ground-water flow, the significance of a highly pervious feature located near the tunnel is discussed in this research. The highly pervious feature, which is located near an underground opening and connected to a large source of water, can provide a path for relatively high-head water to the joints intersecting the opening. This paper describes the influence of a highly pervious feature on the ground-water flow regime around a tunnel and the change of inflow rate as the tunnel approaches a highly pervious feature.  相似文献   

Autochthonous inheritance of zircon through Cretaceous partial melting of Carboniferous plutons: the Arthur River Complex,Fiordland, New Zealand   总被引：1，自引：0，他引：1  

Andrew J. Tulloch  Trevor R. Ireland  David L. Kimbrough  William L. Griffin  Jahandar Ramezani 《Contributions to Mineralogy and Petrology》2011,161(3):401-421

TIMS and SHRIMP U–Pb analyses of zircons from Milford Orthogneiss metadiorite (P = 1–1.4 GPa; T ≥ 750°C) of the Arthur River Complex of northern Fiordland reveal a bimodal age pattern. Zircons are predominantly either Paleozoic (357.0 ± 4.2 Ma) and prismatic with oscillatory zoning, or Cretaceous (133.9 ± 1.8 Ma) and ovoid with sector or patchy zoning. The younger age component is not observed overgrowing older grains. Most grains of both ages are overgrown by younger Cretaceous (~120 Ma) metamorphic zircon with very low U and Th/U (0.01). We interpret the bimodal ages as indicating initial igneous emplacement and crystallisation of a dioritic protolith pluton at ~357 Ma, followed by Early Cretaceous granulite-facies metamorphism at ~134 Ma, during which a significant fraction (~60%) of the zircon grains dissolved, and subsequently reprecipitated, effectively in situ, in partial melt pockets. The remaining ~40% of original Paleozoic grains were apparently not in contact with the partial melt, remained intact, and show only slight degrees of Pb loss. Sector zoning of the Cretaceous grains discounts their origin by solid state recrystallisation of Paleozoic grains. The alternative explanation—that the Paleozoic component represents a 40% inherited component in an Early Cretaceous transgressive dioritic magma—is considered less likely given the relatively high solubility of zircon in magma of this composition, the absence of 134 Ma overgrowths, the single discrete age of the older component, equivalent time-integrated ¹⁷⁷Hf/¹⁷⁶Hf compositions of both age groups, and the absence of the Cambrian-Proterozoic detrital zircon that dominates regional Cambro-Ordovician metasedimentary populations. Similar bimodal Carboniferous-Early Cretaceous age distributions are characteristic of the wider Arthur River Complex; 8 of 12 previously dated dioritic samples have a Paleozoic component averaging 51%. Furthermore, the age and chemical suite affinity of these and several more felsic rocks can be matched with those of the relatively unmetamorphosed Carboniferous plutonic terrane along the strike of the Mesozoic margin in southern Fiordland, also supporting the in situ derivation of the Carboniferous “inherited” component.  相似文献   

Geometrical mechanism of inverse grading in grain-flow deposits: An experimental revelation     

Prabir Dasgupta  Priyanka Manna 《Earth》2011,104(1-3):186-198

The grain-flow has so far been defined with reference to the distinctive sediment-support mechanism, the dispersive pressure. The role of sediment-support mechanism, however, is required in a multiphase flow to prevent the gravitational settling of the particles through the driving medium during the flow. In a single-phase flow of non-cohesive grains no such secondary mechanism is required to counteract the gravitational pull, the driving force of the flow. So the definition of grain-flow needs a critical revision. This, in turn, involves proper understanding of the grain-flow mechanism, so that the relation between the process and the product can be properly established. The most distinctive feature often demonstrated by a grain-flow deposit is the particle size segregation, which leads to the development of inverse grading. The available explanations for this phenomenon find theoretical constraints. In the present study an attempt was made to understand the mechanism of single-phase non-cohesive granular flow of different flow regime and the particle segregation pattern in the resultant deposit through laboratory simulation. The experimental observations revealed that no sustained granular flow sets in on a slope deviating much from the limiting value of the angle of repose of the granular material. A persistent simple shear flow develops on slopes of this critical value. Each of the grains rolls in response to simple shearing. If the shear stress attains a critical value, theoretically the larger grains can even climb up the adjacent smaller ones towards the down-slope direction. In reality, however, high angle climb is not very common. The larger grains preferably roll over the smaller grains when the common tangent becomes almost horizontal or makes a very low angle with the direction of flow, and by this process gradually reaches the upper surface of the flow causing the development of inverse grading. The upper surface of the resultant deposit remains parallel to the sloping substratum. These properties readily distinguish this variety of granular flow from the other natural flows, and the flow may thus be assigned the distinct status of grain-flow.  相似文献   

Degradation of natural organic matter: A thermodynamic analysis     

Douglas E. LaRowe  Philippe Van Cappellen 《Geochimica et cosmochimica acta》2011,75(8):2030-16486

  相似文献   

Petrogenesis and chronology of lunar meteorite Northwest Africa 4472: A KREEPy regolith breccia from the Moon     

K.H. Joy  R. Burgess  V.A. Fernandes  I.A. Crawford  A.T. Kearsley  EIMFg 《Geochimica et cosmochimica acta》2011,75(9):2420-7225

Northwest Africa (NWA) 4472 is a polymict lunar regolith meteorite. The sample is KREEP-rich (high concentrations of potassium, rare earth elements and phosphorus) and comprises a heterogeneous array of lithic and mineral fragments. These clasts and mineral fragments were sourced from a range of lunar rock types including the lunar High Magnesian Suite, the High Alkali Suite, KREEP basalts, mare basalts and a variety of impact crater environments. The KREEP-rich nature of NWA 4472 indicates that the sample was ejected from regolith on the nearside of the Moon in the Procellarum KREEP Terrane and we have used Lunar Prospector gamma-ray remote sensing data to show that the meteorite is most similar to (and most likely sourced from) regoliths adjacent to the Imbrium impact basin.U-Pb and Pb-Pb age dates of NWA 4472 phosphate phases reveal that the breccia has sampled Pre-Nectarian (4.35 Ga) rocks related to early episodes of KREEP driven magmatism. Some younger phosphate U-Pb and Pb-Pb age dates are likely indicative of impact resetting events at 3.9-4 Ga, consistent with the suggested timing of basin formation on the Moon. Our study also shows that NWA 4472 has sampled impact melts and glass with an alkali-depleted, incompatible trace element-rich (high Sc, low Rb/Th ratios, low K) compositional signature not related to typical Apollo high-K KREEP, or that sampled by KREEPy lunar meteorite Sayh al Uhaymir (SaU) 169. This provides evidence that there are numerous sources of KREEP-rich protoliths on the Moon.  相似文献   

A comparative study of the molecular composition of a grassland soil with adjacent unforested and afforested moorland ecosystems     

《Organic Geochemistry》2011,42(12):1519-1528

On-line thermally assisted hydrolysis and methylation (THM) in the presence of both unlabelled and ¹³C-labelled tetramethylammonium hydroxide (TMAH) was used to assess the relative contributions of phenolics (lignin, demethylated lignin and non-lignin phenolics) in a peaty gley soil profile beneath an unimproved grassland (LL), from a study site located at Harwood (Northumberland, northeast England, UK). This site also includes an unforested moorland (ML) and a second rotation Sitka spruce stand (SS). The common lignin proxies have been corrected for contributions of non-lignin phenols and demethylated lignin in the LL ecosystem and then compared with those from the ML and SS ecosystems. The phenolic compositions from the contributory vegetation inputs (i.e. grasses, heather and Sitka spruce) to all three soils (LL, ML and SS) were also analysed. By using ¹³C-labelled TMAH it was possible to show that the chemical composition of soil organic matter (SOM) reflected the different vegetation inputs in each of the L/F layers but these characteristics were lost from the deeper organic and mineral layers. Similar changes in the yield of lignin monomers (Λ) with increasing soil depth were displayed in the LL soil profile as reported previously in the ML soil in that no maxima were observed in these amount-depth profiles. The tannin input to the LL soil is low and as a consequence, unlike the ML and SS soils, there is no progressive decrease in the amounts of these non-lignin phenolics with increasing depth. Finally the methylated carbohydrate derivatives (MC) become more abundant relative to the phenolics with increasing soil depth in all three ecosystems (LL, ML and SS).  相似文献   

东亚副热带急流与东北夏季降水异常的关系   总被引：9，自引：3，他引：6  

兰明才  张耀存 《气象科学》2011,31(3):258-265

利用东北地区88个气象站点观测的7、8月(夏季)降水量和NCEP/NCAR再分析资料,分析了东北地区夏季降水与同期东亚副热带西风急流之间的关系,发现东北地区夏季降水异常偏多年,位于青藏高原上空200 hPa西风急流中心强度偏强,东北地区上空急流轴向东北方向倾斜;东北地区夏季降水异常偏少年,青藏高原上空200 hPa西风...  相似文献   

城市近地层湍流特征分析   总被引：3，自引：3，他引：0  

邹钧  孙鉴泞  刘罡 《气象科学》2011,31(4):525-533

利用中国科学院大气物理研究所在北京的325 m铁塔观测资料,本文分析了47、140和280 m三个高度的湍流统计特征.结果表明,城市近地层的湍流速度方差和湍流温度方差都较好地满足局地相似关系,140 m和280 m的湍流特征非常接近,而47 m的湍流特征与之相比表现出明显的差异,说明由于城市冠层动力和热力非均匀性的影响...  相似文献